| Person | Type | Job | Role(s) | Episodes |
|---|---|---|---|---|
 Alex Gibney | Crew | Production | Executive Producer, Writer | 4 |
 Alison Ellwood | Crew | Production | Producer, Director | 4 |
 Julian Cautherley | Crew | Production | Co-Executive Producer | 4 |
 Lucy Walker | Crew | Production | Executive Producer, Director | 4 |
Richard Perello | Crew | Production | Executive Producer | 4 |
Stacey Offman | Crew | Production | Executive Producer | 4 |
 Michael Pollan | Crew | Writing | Book, Executive Producer, Creator | 4 |
Tahria Sheather | Crew | Production | Producer | 4 |
Isaac Bolden | Crew | Production | Co-Executive Producer | 4 |
Evan Lerner | Crew | Production | Co-Executive Producer | 4 |
Alexandra Meistrell | Crew | Production | Co-Executive Producer | 4 |
Michael Pollan | Cast | Actor | Self | 4 |
 Rick Doblin | Cast | Actor | Self - Founder, MAPS | 1 |
 Alexander Shulgin | Cast | Actor | Self - Chemist, Author & Professor (archive footage) | 1 |
Ann Shulgin | Cast | Actress | Self - Author, Mentor & Guide Therapist | 1 |
| Person | Type | Job | Role(s) | Episodes |
