Because I Don't Like My Big Brother at All!

As Shūsuke puts up with more of Ran's dubious rituals, Rin forces Nao to hang out with her by threatening to tell Shūsuke that she had been stalking him, looking for an opportunity to kiss her. Shūsuke and Nao soon become paranoid around each other when they see each other hanging around the respective Yatagai sister. Nao and Iroha determine that the only way to get Rin off her back is to convince Ran that Shūsuke isn't her saviour by pretending to be prophets on their mobile phones. Rin catches onto their plan and tries to get the drop on Nao but ends up kissing Iroha instead, though she immediately takes a liking to her lips and runs off with her. Ran later explains to Nao that she wanted to mentally train Shūsuke to play as a warrior for a cosplay event, though when the day of the event arrives, Shūsuke gets the address wrong and arrested for wearing his skimpy outfit in public.

Shūsuke goes to a Matsuri festival with Nao and Iroha, who compete with each other to try and seduce him. Meanwhile, the A.G.E Explorers go on a quest to find a legendary pornographic treasure and proceed to drag Shūsuke away to join them. However, the treasure they find contains zoophillic porn that proves too intense for them and they run away, with Shūsuke picking up Nao in tow. After watching the fireworks with Nao, Shūsuke goes to deliver some BL books to Mayuka, who once again becomes enthralled by his nipples.

Shūsuke and his friends go on a trip to Akihabara in search of adult goods while Nao and Iroha decide to follow them. After visiting an adult DVD store, the group gets into an argument about their desired fetishes and break off in search of them, leaving Shūsuke alone. However, they soon come to apologize to each other and go to a maid café holding a 'little-sister' service.

While running back from buying a new porno magazine, Shūsuke bumps into another person. They get their packages mixed up and Shūsuke ends up with a Boy's Love magazine that he immediately rips to shreds. When the other party, known as Mister X, discovers about the mix up, he sends Shūsuke a threatening note demanding its return. That night, when Shūsuke attempts to make an exchange with Mister X using a different BL magazine, with Nao and Iroha stalking him, he learns Mister X's true identity is that of his class rep, Mayuka Kondō. With the threat of his porn being shredded or shown to Nao, Shūsuke agrees to become Mayuka's pet, assuming there will be sexual requests involved. The requests start simple, such as buying her a drink or trying her bentō lunch. However, the next evening, Mayuka asks Shūsuke to buy her a more extreme BL magazine she's too embarrassed to buy herself.

Iroha coerces Shūsuke into going on a date with her, and Nao decides to follow them, while her friends, Haruka and Hirono, decide to tail her as well. Iroha takes Shūsuke various places including a movie theater, an arcade and a swimsuit store. At the end of the date, Iroha tries to get Shūsuke to kiss her, but he refuses. Iroha tries to drag him somewhere else, but Nao manages to bail him out. Nao begins treating Shūsuke coldly, leading him to realize that she knew about his date with Iroha. When Iroha scares Shūsuke with the notion that she knows everything he's been doing (having been watching him through a telescope), Shūsuke rolls on the floor when Nao enters, getting a look at her panties which reawakens his normal perversion, much to Nao's delight.

Nao Takanashi has long been trying to tempt her brother, Shūsuke, into entering an immoral (i.e. incest) relationship with her, with Shūsuke barely being able to resist. Nao goes to great lengths for Shūsuke to think of her perversely by doing things such as letting him purposely look underneath her skirt (and once letting him see her completely naked) but then she always gets him into trouble afterward so as to make it look like Shūsuke is the immoral pervert. One day, while Nao searches through Shūsuke's room for his collection of porn magazines, she then finds a hidden family photo album and is surprised to find out that there are no childhood pictures of her in it. After Shūsuke was finished being scolded about his porn collection, Nao confronts her parents, Shūji and Nanaka, about the album.